Matchday 1 : 18-19 September 2012
| Dinamo Zagreb |  | 0-2 |  | Porto |
| Stadium: Stadion Maksimir, Zagreb (CRO) | ||||
| PSG |  | 4-1 |  | Dynamo Kyiv |
| Stadium: Parc des Princes, Paris (FRA) | ||||
| Montpellier |  | 1-2 |  | Arsenal |
| Stadium: La Mosson, Montpellier (FRA) | ||||
| Olympiacos |  | 1-2 |  | Schalke |
| Stadium: Georgios Karaiskakis Stadium, Piraeus (GRE) | ||||
| Málaga |  | 3-0 |  | Zenit |
| Stadium: La Rosaleda, Malaga (ESP) | ||||
| Milan |  | 0-0 |  | Anderlecht |
| Stadium: Stadio Giuseppe Meazza, Milan (ITA) | ||||
| Dortmund |  | 1-0 |  | Ajax |
| Stadium: BVB Stadion Dortmund, Dortmund (GER) | ||||
| Real Madrid |  | 3-2 |  | Man. City |
| Stadium: Estadio Santiago Bernabéu, Madrid (ESP) | ||||
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